nKOH = 0,0015 mol
nBa(OH)2 = 0,001 mol
=> n[OH-] = 0,0015+0,001.2=0,0035 mol
=> p[OH-] = 2,456
=> p[H+] = 14-p[OH-]=11,544

\(n_{H^+}=0.2\cdot0.01\cdot2=0.004\left(mol\right)\)

\(n_{OH^-}=0.1\cdot0.01=0.001\left(mol\right)\)

\(H^++OH^-\rightarrow H_2O\)

\(0.001.....0.001\)

\(n_{H^+\left(dư\right)}=0.004-0.001=0.003\left(mol\right)\)

\(pH=-log\left(H^+\right)=-log\left(\dfrac{0.003}{0.2+0.1}\right)=2\)

Có: \(n_{H^+}=2n_{H_2SO_4}=2.0,2.0,01=0,004\left(mol\right)\)

\(n_{OH^-}=0,1.0,01=0,001\left(mol\right)\)

PT ion: \(H^++OH^-\rightarrow H_2O\)

____0,004___0,001 (mol)

\(\Rightarrow n_{H^+\left(dư\right)}=0,003\left(mol\right)\)\\(\Rightarrow\left[H^+\right]=\dfrac{0,003}{0,3}=0,01\)

\(\Rightarrow pH=2\)

Bạn tham khảo nhé!

Ok, để thử coi chứ tui ngu hóa thấy mồ :(

a/ \(n_{NaOH}=0,2.0,1=0,02\left(mol\right)\)

\(NaOH\rightarrow Na^++OH^-\)

\(n_{Na^+}=n_{OH^-}=0,02\left(mol\right)\)

\(\Rightarrow C_{MNa^+}=\frac{0,02}{0,4+0,1}=0,04\left(mol/l\right)\)

\(n_{Ba\left(OH\right)_2}=0,3.0,4=0,12\left(mol\right)\)

\(Ba\left(OH\right)_2=Ba^{2+}+2OH^-\)

\(\Rightarrow n_{OH^-}=0,24\left(mol\right);n_{Ba^{2+}}=0,12\left(mol\right)\)

\(\Rightarrow C_{MBa^{2+}}=\frac{0,12}{0,5}=0,24\left(mol/l\right)\)

\(n_{OH^-}=0,02+0,24=0,26\left(mol\right)\)

\(\Rightarrow C_{MOH^-}=\frac{0,26}{0,5}=0,52\left(mol/l\right)\)

b/ \(n_{HCl}=0,2V\left(mol\right)\)

\(\Rightarrow n_{H^+}=n_{Cl^-}=0,2V\)

\(\Rightarrow C_{MCl^-}=\frac{0,2V}{2V}=0,1\left(mol/l\right)\)

\(n_{H_2SO_4}=0,3V\left(mol\right)=\frac{n_{H^+}}{2}=n_{SO_4^{2-}}\)

\(\Rightarrow C_{MSO_4^{2-}}=\frac{0,3V}{2V}=0,15\left(mol/l\right)\)

\(n_{H^+}=0,2V+0,6V=0,8V\left(mol\right)\)

\(\Rightarrow C_{MH^+}=\frac{0,8V}{2V}=0,4\left(mol/l\right)\)

Bác nào hảo tâm giúp em mấy câu còn lại chớ đến đây thì em chịu chết òi :(

Em lp dưới, có thể làm sai nên bài e chưa chắc đúng đâu chị nhé!!!!

\(n_{HCl}=0.1\cdot0.03=0.003\left(mol\right)\)

\(n_{NaOH}=0.1\cdot0.01=0.001\left(mol\right)\)

\(NaOH+HCl\rightarrow NaCl+H_2O\)

Lập tỉ lệ : 

\(\dfrac{0.003}{1}>\dfrac{0.001}{1}\Rightarrow HCldư\)

\(n_{HCl\left(dư\right)}=0.003-0.001=0.002\left(mol\right)\)

\(\left[H^+\right]=\dfrac{0.002}{0.1+0.1}=0.01\)

\(pH=-log\left(0.01\right)=2\)

\(b.\)

\(Ba\left(OH\right)_2+2HCl\rightarrow BaCl_2+2H_2O\)

\(0.001..........0.002\)

\(V_{Ba\left(OH\right)_2}=\dfrac{0.001}{1}=0.001\left(l\right)\)

pH~2,5

Sửa đề H₂SO₂ thành H₂SO₄

\(n_{Ba^{2+}}=n_{Ba\left(OH\right)2}=0,01.0,1=0,001\left(mol\right)\)

\(\Rightarrow n_{OH^-}=2n_{Ba\left(OH\right)2}=2.0,001=0,002\left(mol\right)\)

\(n_{SO_4^{2-}}=n_{H2SO4}=0,1.0,05=0,005\left(mol\right)\)

\(\Rightarrow n_{H^+}=2n_{H2SO4}=2.0,005=0,01\left(mol\right)\)

\(Ba^{2+}+SO_4^{2-}\rightarrow BaSO_4\)

0,001   0,01           0,01

Xét tỉ lệ : \(0,001< 0,01\Rightarrow SO_4^{2-}dư\)

\(n_{Ba^{2+}\left(pư\right)}=n_{BaSO4}=0,001\left(mol\right)\Rightarrow m_{BaSO4}=0,001.233=0,233\left(g\right)\)

\(H^++OH^-\rightarrow H_2O\)

0,01 0,002

Xét tỉ lệ : \(0,01>0,002\Rightarrow H^+dư\)

\(n_{H^+dư}=0,01-0,002=0,008\left(mol\right)\Rightarrow\left[H^+\right]=\dfrac{0,008}{0,1+0,1}=0,04M\)

\(\Rightarrow pH=-log\left(0,04\right)\approx1,4\)

a, \(\left\{{}\begin{matrix}n_{Ba^{2+}}=4.10^{-3}\left(mol\right)\\n_{Na^+}=3.10^{-3}\left(mol\right)\\n_{OH^-}=0,011\left(mol\right)\end{matrix}\right.\)

\(\Rightarrow\left\{{}\begin{matrix}\left[Ba^{2+}\right]=\dfrac{4.10^{-3}}{0,2+0,3}=0,008M\\\left[Na^+\right]=\dfrac{3.10^{-3}}{0,2+0,3}=0,006M\\\left[OH^-\right]=\dfrac{0,011}{0,2+0,3}=0,022M\end{matrix}\right.\)

b, Để trung hòa dung dịch A thì:

\(n_{H^+}=n_{OH^-}\)

\(\Leftrightarrow0,01.V_{ddHCl}=\left(0,02.2+0,01\right).0,2\)

\(\Leftrightarrow V_{ddHCl}=1\left(l\right)\)

cần lời giải chi tiết ạ