$n_{NaOH} = 0,001(mol)$
$n_{Ba(OH)_2} = 0,01.0,15 = 0,0015(mol)$

$NaOH \to Na^+ + OH^-$
$Ba(OH)_2 \to Ba^{2+} + 2OH^-$

Ta có : 

$n_{OH^-}= 0,001 + 0,0015.2 = 0,004(mol)$
$V_{dd} = 0,1 + 0,15 = 0,25(mol)$
$[OH^-] = \dfrac{0,004}{0,25} = 0,016M$

$pOH = -log(0,016) = 1,795 \Rightarrow pH = 14 - 1,795 = 12,205$

\(n_{OH^-}=0,1.0,01+0,15.0,01.2=0,004\left(mol\right)\\ V_{ddsau}=100+150=250\left(ml\right)=0,25\left(l\right)\\ \Rightarrow\left[OH^-\right]=\dfrac{0,004}{0,25}=0,016\left(M\right)\\ pH=14+log\left[0,016\right]\approx12,204\)

\(n_{NaOH}=0,03.0,1=0,003\left(mol\right)\\ n_{HNO_3}=0,01.0,01=0,0001\left(mol\right)\\ NaOH+HNO_3\rightarrow NaNO_3+H_2O\\ Vì:\dfrac{0,0001}{1}< \dfrac{0,003}{1}\\ \Rightarrow NaOHdư\\ n_{NaOH\left(dư\right)}=0,003-0,0001=0,0029\left(mol\right)\\ \left[OH^-\left(dư\right)\right]=\left[NaOH_{dư}\right]=\dfrac{0,0029}{0,01+0,1}=\dfrac{29}{1100}\left(M\right)\\ \Rightarrow pH=14+log\left[\dfrac{29}{1100}\right]\approx12,421\)

\(n_{NaOH}=0,1.0,01=0,001(mol)\\ \Rightarrow n_{OH^{-}}=0,001(mol)\\ n_{HCl}=0,03.0,2=0,006(mol)\\ \Rightarrow n_{H^{+}}=0,006(mol)\\ H^{+}+OH^{-}\to H_2O\\ 0,001<0,006\\ OH^{-} hêt; H^{+} dư\\ n_{H^{+}}=0,006-0,001=0,005(mol)\\ [H^{+}]=\frac{0,005}{0,1+0,2}=\frac{1}{60}M\\ \to pH=-log(\frac{1}{60})=1,77 \)

\(n_{HCl}=0.1\cdot0.03=0.003\left(mol\right)\)

\(n_{NaOH}=0.1\cdot0.01=0.001\left(mol\right)\)

\(NaOH+HCl\rightarrow NaCl+H_2O\)

Lập tỉ lệ : 

\(\dfrac{0.003}{1}>\dfrac{0.001}{1}\Rightarrow HCldư\)

\(n_{HCl\left(dư\right)}=0.003-0.001=0.002\left(mol\right)\)

\(\left[H^+\right]=\dfrac{0.002}{0.1+0.1}=0.01\)

\(pH=-log\left(0.01\right)=2\)

\(b.\)

\(Ba\left(OH\right)_2+2HCl\rightarrow BaCl_2+2H_2O\)

\(0.001..........0.002\)

\(V_{Ba\left(OH\right)_2}=\dfrac{0.001}{1}=0.001\left(l\right)\)

Ta có: \(\left\{{}\begin{matrix}n_{Ba^{2+}}=n_{Ba\left(OH\right)_2}=0,1.0,01=0,001\left(mol\right)\\n_{OH^-}=2n_{Ba\left(OH\right)_2}=2.0,1.0,01=0,002\left(mol\right)\end{matrix}\right.\)

\(\left\{{}\begin{matrix}\Sigma n_{H^+}=0,2.0,01+2.0,2.0,02=0,01\left(mol\right)\\n_{SO_4^{2-}}=n_{H_2SO_4}=0,2.0,02=0,004\left(mol\right)\end{matrix}\right.\)

PT ion: \(H^++OH^-\rightarrow H_2O\)

_____ 0,01___0,002_________ (mol)

⇒ H⁺ dư. \(\Rightarrow n_{H^+\left(dư\right)}=0,008\left(mol\right)\)

\(\Rightarrow\left[H^+\right]=\frac{0,008}{0,3}=\frac{2}{75}M\Rightarrow pH\approx1,57\)

PT ion: \(Ba^{2+}+SO_4^{2-}\rightarrow BaSO_{4\downarrow}\)

______ 0,001__0,004__ → 0,001 (mol)

\(\Rightarrow m_{\downarrow}=m_{BaSO_4}=0,001.233=0,233\left(g\right)\)

Bạn tham khảo nhé!

nKOH = 0,0015 mol
nBa(OH)2 = 0,001 mol
=> n[OH-] = 0,0015+0,001.2=0,0035 mol
=> p[OH-] = 2,456
=> p[H+] = 14-p[OH-]=11,544

\(n_{OH^-}=0,05V+0,02V=0,07V\left(mol\right)\)

\(\Rightarrow\left[OH^-\right]=\dfrac{0,07V}{2V}=0,035M\)

\(\Rightarrow\left[H^+\right]=\dfrac{2.10^{-12}}{7}M\)

\(\Rightarrow pH\approx12,5\)