\(n_{ZnO}=\dfrac{8,1}{81}=0,1\left(mol\right)\\ n_{H_2SO_4}=\dfrac{19,6\%.200}{98}=0,4\left(mol\right)\\a, ZnO+H_2SO_4\rightarrow ZnSO_4+H_2O\\ b,Vì:\dfrac{0,1}{1}< \dfrac{0,4}{1}\\ \Rightarrow H_2SO_4dư\\ n_{H_2SO_4\left(p.ứ\right)}=n_{ZnSO_4}=n_{ZnO}=0,1\left(mol\right)\\ n_{H_2SO_4\left(dư\right)}=0,4-0,1=0,3\left(mol\right)\\ \Rightarrow m_{H_2SO_4\left(dư\right)}=98.0,3=29,4\left(g\right)\\ c,n_{ZnSO_4}=0,1.161=16,1\left(g\right)\\ m_{ddsau}=m_{ZnO}+m_{ddH_2SO_4}=8,1+200=208,1\left(g\right)\\ \Rightarrow C\%_{ddH_2SO_4\left(dư\right)}=\dfrac{29,4}{208,1}.100\approx14,128\%\\ C\%_{ddZnSO_4}=\dfrac{16,1}{208,1}.100\approx7,737\%\)

ZnO+H₂SO₄->ZnSO₄+H₂O

0,1-----0,1-------0,1-------0,1 mol

n _ZnO=\(\dfrac{8,1}{81}\)=0,1 mol

m _H2SO4 =39,2g =>n _H2SO4=\(\dfrac{39,2}{98}\)=0,4 mol

=>H2SO4 , dư 0,3 mol

=>m _H2SO4=0,3.98=29,4g

=>C%_H2SO4 dư=\(\dfrac{29,4}{200+0,1.18}\).100=14,568%

=>C% _ZnSO4=\(\dfrac{0,1.161}{200+0,1.18}.100=7,9781\%\)

1

\(a)m_{H_2O}=250-5=245g\\b )C_{\%NaCl}=\dfrac{5}{250}\cdot100=2\%\)

\(2\\ m_{ddCuSO_4}=\dfrac{15.100}{5}=300g\\ m_{H_2O}=300-15=285g\)

Câu 1:

a, Ta có: m _dd = m _{chất tan} + m_H2O ⇒ m_H2O = 250 - 5 = 245 (g)

b, \(C\%_{NaCl}=\dfrac{5}{250}.100\%=2\%\)

Câu 2:

Ta có: \(C\%_{CuSO_4}=\dfrac{15}{m_{ddCuSO_4}}.100\%=5\%\)

\(\Rightarrow m_{ddCuSO_4}=300\left(g\right)\)

⇒ m_H2O = 300 - 15 = 285 (g)

a, nFe = 0,56/56 = 0,01 (mol)

PTHH: Fe + H2SO4 -> FeSO4 + H2

Mol: 0,01 ---> 0,01 ---> 0,01 ---> 0,01

mFeSO4 = 0,01 . 152 = 1,52 (g)

VH2 = 22,4 . 0,01 = 0,224 (l)

b, mH2SO4 = 0,01 . 98 = 0,98 (g)

c, mddH2SO4 = 0,98/19,6% = 5 (g)

d, mdd (sau p/ư) = 5 + 0,56 = 5,56 (g)

C%FeSO4 = 1,52/5,56 = 27,33%

a, nFe = 0,56/56 = 0,01 (mol)

PTHH: Fe + H2SO4 -> FeSO4 + H2

Mol: 0,01 ---> 0,01 ---> 0,01 ---> 0,01

mFeSO4 = 0,01 . 152 = 1,52 (g)

VH2 = 22,4 . 0,01 = 0,224 (l)

b, mH2SO4 = 0,01 . 98 = 0,98 (g)

c, mddH2SO4 = 0,98/19,6% = 5 (g)

d, mdd (sau p/ư) = 5 + 0,56 = 5,56 (g)

C%FeSO4 = 1,52/5,56 = 27,33%

\(n_{Fe}=\dfrac{12}{56}=\dfrac{3}{14}\left(mol\right)\)

\(Fe+H_2SO_4\rightarrow FeSO_4+H_2\)

\(\dfrac{3}{14}....\dfrac{3}{14}.......\dfrac{3}{14}......\dfrac{3}{14}\)

\(m_{FeSO_4}=\dfrac{3}{14}\cdot152=32.57\left(g\right)\)

\(V_{H_2}=\dfrac{3}{14}\cdot22.4=4.8\left(l\right)\)

\(m_{dd_{H_2SO_4}}=\dfrac{\dfrac{3}{14}\cdot98}{19.6\%}=107.1\left(g\right)\)

Tóm tắt

\(V_{H_2\left(đktc\right)}=8,96l\\ C_{\%H_2SO_4}=19,6\%\\ a)m_{Zn}=?\\ m_{ddH_2SO_4}=?\\ b)C_{\%ZnSO_4}=?\)

\(a)n_{H_2}=\dfrac{8,96}{22,4}=0,4mol\\ Zn+H_2SO_4\rightarrow ZnSO_4+H_2\)

0,4        0,4              0,4           0,4

\(m_{Zn}=0,4.65=26g\\ m_{ddH_2SO_4}=\dfrac{0,4.98}{19,6}\cdot100=200g\\ b)C_{\%ZnSO_4}=\dfrac{0,4.161}{26+200-0,4.2}\cdot100=28,6\%\)

\(n_{H_2}=\dfrac{8,96}{22,4}=0,4\left(mol\right)\)

PTHH :

\(Zn+H_2SO_4\rightarrow ZnSO_4+H_2\uparrow\)

 0,4    0,4             0,4        0,4

\(a,m_{Zn}=0,4.65=26\left(g\right)\)

\(m_{H_2SO_4}=0,4.98=39,2\left(g\right)\)

\(m_{ddH_2SO_4}=\dfrac{39,2.100}{19,6}=200\left(g\right)\)

\(b,m_{ZnSO_4}=0,4.161=64,4\left(g\right)\)

\(m_{ddZnSO_4}=200+26-\left(0,4.2\right)=225,2\left(g\right)\)

\(C\%_{ZnSO_4}=\dfrac{64,4}{225,2}.100\%\simeq28,6\%\)

\(a,m_{NaCl}=\dfrac{8.200}{100}=16\left(g\right)\\ b,m_{HCl}=\dfrac{250.14}{100}=35\left(g\right)\\ m_{H_2SO_4}=\dfrac{19,6.300}{100}=58,8\left(g\right)\)

Đáp án D

Số mol H₂SO₄ là:  n H 2 SO 4 = 0 , 5 . 0 , 1 = 0 , 05   mol

Gọi M₂O_n là oxit chung cho các oxit trong X

Sơ đồ phản ứng :

a) 

\(m_{H_2SO_4}=\dfrac{300.19,6}{100}=58,8\left(g\right)\)

=> \(m_{dd.H_2SO_4.9,8\%}=\dfrac{58,8.100}{9,8}=600\left(g\right)\)

=> \(m_{H_2O\left(thêm\right)}=600-300=300\left(g\right)\)

b)

\(n_{HCl}=0,2.2=0,4\left(mol\right)\)

=> \(V_{dd.HCl.1,5M}=\dfrac{0,4}{1,5}=\dfrac{4}{15}\left(l\right)\)

=> \(V_{H_2O\left(thêm\right)}=\dfrac{4}{15}-0,2=\dfrac{1}{15}\left(l\right)=\dfrac{200}{3}\left(ml\right)\)

=> \(m_{H_2O\left(thêm\right)}=\dfrac{200}{3}.1=\dfrac{200}{3}\left(g\right)\)