\(n_{CuCl_2}=0,075mol\)
\(n_{NaOH}=0,05.2=0,1mol\)
CuCl2+2NaOH\(\rightarrow\)Cu(OH)2\(\downarrow\)+2NaCl
-Tỉ lệ: \(\dfrac{0,075}{1}>\dfrac{0,1}{2}\)suy ra CuCl2 dư
CuCl2+2NaOH\(\rightarrow\)Cu(OH)2\(\downarrow\)+2NaCl
0,05..\(\leftarrow\)0,1\(\rightarrow\).......0,05\(\rightarrow\)........0,1
a=\(m_{Cu\left(OH\right)_2}=0,05.98=4,9gam\)
\(n_{NaCl}=0,1mol\)
\(n_{CuCl_2\left(dư\right)}=0,075-0,05=0,025mol\)
\(V_{dd}=0,075+0,05=0,125l\)
\(C_{M_{NaCl}}=\dfrac{0,1}{0,125}=0,8M\)
\(C_{M_{CuCl_2}}=\dfrac{0,025}{0,125}=0,2M\)
theo đề bài ta có : \(\left\{{}\begin{matrix}nCuCl2=0,075.1=0,075\left(mol\right)\\nNaOH=0,05.2=0,1\left(mol\right)\end{matrix}\right.\)
PTHH :
\(CuCl2+2NaOH->Cu\left(OH\right)2\downarrow+2NaCl\)
0,05mol.........0,1mol...........0,05mol............0,1mol
Theo pthh ta có : \(nCuCl2=\dfrac{0,075}{1}mol>nNaOH=\dfrac{0,1}{2}mol=>nCuCl2\left(d\text{ư}\right)\) ( tính theo nNaOH)
a) PTHH :
\(Cu\left(OH\right)2-^{t0}->CuO+H2O\)
0,05mol........................0,05mol
=> a = mCuO = 0,05.80 = 4 (g)
b) Ta có :
\(\left\{{}\begin{matrix}CM_{NaCl}=\dfrac{0,1}{0,075+0,05}=0,8\left(M\right)\\CM_{CuCl2\left(d\text{ư}\right)}=\dfrac{0,075-0,05}{0,075+0,05}=0,2\left(M\right)\end{matrix}\right.\)
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