Fe + H2SO4 → FeSO4 + H2 (1)
Fe2O3 + 3H2SO4 → Fe2(SO4)3 + 3H2O (2)
a) \(n_{H_2}=\dfrac{1,12}{22,4}=0,05\left(mol\right)\)
Theo PT1: \(n_{Fe}=n_{H_2}=0,05\left(mol\right)\)
\(\Rightarrow m_{Fe}=0,05\times56=2,8\left(g\right)\)
\(\Rightarrow m_{Fe_2O_3}=18,8-2,8=16\left(g\right)\)
b) Theo PT1: \(n_{H_2SO_4}=n_{Fe}=0,05\left(mol\right)\)
\(n_{Fe_2O_3}=\dfrac{16}{160}=0,1\left(mol\right)\)
Theo PT2: \(n_{H_2SO_4}=3n_{Fe_2O_3}=3\times0,1=0,3\left(mol\right)\)
\(\Rightarrow\Sigma n_{H_2SO_4}=0,05+0,3=0,35\left(mol\right)\)
\(\Rightarrow V_{ddH_2SO_4}=\dfrac{0,35}{1}=0,35\left(l\right)=350\left(ml\right)\)
\(\Rightarrow m_{ddH_2SO_4}=1,65\times350=577,5\left(g\right)\)