CuO + H2SO4 \(\rightarrow\)CuSO4 + H2O (1)
Cr2O3 + 3H2SO4 \(\rightarrow\)Cr2(SO4)3 + 3H2O (2)
Đặt nCuO=a
nCr2O3=b
Ta có :
\(\left\{{}\begin{matrix}80a+152b=69,2\\160a+392b=169,2\end{matrix}\right.\)
=>a=0,2;b=0,35
mCuO=80.0,2=16(g)
mCr2O3=69,2-16=53,2(g)
b;Theo PTHH 1 và 2 ta có:
nCuO=nH2SO4=0,2(mol)
3nCr2O3=nH2SO4=1,05(mol)
nCuO=nCuSO4=0,2(mol)
nCr2O3=nCr2(SO4)3=0,35(mol)
mH2SO4=(1,05+0,2).98=122,5(g)
mdd H2SO4=122,5:\(\dfrac{1,96}{100}=6250\left(g\right)\)
mCuSO4=0,2.160=32(g)
mCr2(SO4)3=392.0,35=137,2(g)
C% dd CuSO4=\(\dfrac{32}{6250+69,2}.100\%=0,5\%\)
C% dd Cr2(SO4)3=\(\dfrac{137,2}{6250+69,2}.100\%=2,17\%\)
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