\(BD=a\sqrt{2}\)
\(\widehat{\left(\overrightarrow{BD};\overrightarrow{BS}\right)}=\widehat{SBD}=\dfrac{SB^2+BD^2-SD^2}{2SB.BD}=\dfrac{a^2+2a^2-a^2}{2a.a\sqrt{2}}=\dfrac{\sqrt{2}}{2}\)
\(\Rightarrow\widehat{\left(\overrightarrow{BD};\overrightarrow{BS}\right)}=45^0\)