a, Ta có: \(n_{NO_2}=2,1\left(mol\right)\)
Gọi: \(\left\{{}\begin{matrix}n_{Fe}=x\left(mol\right)\\n_{Zn}=y\left(mol\right)\end{matrix}\right.\)
⇒ 56x + 65y = 47,5 (1)
Theo ĐLBT e, có: 3x + 2y = 2,1 (2)
Từ (1) và (2) \(\Rightarrow\left\{{}\begin{matrix}x=0,5\left(mol\right)\\y=0,3\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}\%m_{Fe}=\dfrac{0,5.56}{47,5}.100\%\approx58,95\%\\\%m_{Zn}\approx41,05\%\end{matrix}\right.\)
b, Ta có: m dd sau pư = 47,5 + 441 - 2,1.46 = 391,9 (g)
BTNT Fe: nFe(NO3)3 = nFe = 0,5 (mol)
BTNT Zn: nZn(NO3)2 = nZn = 0,3 (mol)
\(\Rightarrow\left\{{}\begin{matrix}C\%_{Fe\left(NO_3\right)_3}=\dfrac{0,5.242}{391,9}.100\%\approx30,88\%\\C\%_{Zn\left(NO_3\right)_2}=\dfrac{0,3.189}{391,9}.100\%\approx14,47\%\end{matrix}\right.\)