\(a,n_{Na}=\dfrac{m_{Na}}{M_{Na}}=\dfrac{4,6}{23}=0,2\left(mol\right)\\ n_{Cl_2}=\dfrac{V_{Cl_2\left(đktc\right)}}{22,4}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\\ PTHH:2Na+Cl_2\rightarrow2NaCl\\ Vì:\dfrac{0,2}{2}< \dfrac{0,2}{1}\Rightarrow Cl_2dư\\ \Rightarrow n_{Cl_2\left(dư\right)}=0,2-\dfrac{0,2}{2}=0,1\left(mol\right)\\ \Rightarrow m_{Cl_2\left(dư\right)}=0,1.71=7,1\left(g\right)\\ b,n_{NaCl}=n_{Na}=0,2\left(mol\right)\\ \Rightarrow m_{NaCl}=58,5.0,2=11,7\left(g\right)\)