$n_{HCl} = \dfrac{44,8}{22,4} = 2(mol)$
$m_{dd\ A} = m_{HCl} + m_{H_2O} = 2.36,5 + 327 =400(gam)$
$C\%_{HCl} = \dfrac{2.36,5}{400}.100\% = 18,25\%$
Mặt khác, trong 250 gam dung dịch A có $n_{HCl} = 2. \dfrac{250}{400} = 1,25(mol)$
$n_{CaCO_3} = \dfrac{50}{100} = 0,5(mol)$
$CaCO_3 + 2HCl \to CaCl_2 + CO_2 + H_2O$
Ta có :
$n_{CaCO_3} : 1 < n_{HCl} : 2$ nên $HCl$ dư
$n_{CO_2} = n_{CaCO_3} = 0,5(mol)$
$n_{HCl\ dư} = 1,25 - 0,5.2 = 0,25(mol)$
$m_{dd\ sau pư} = 50 + 250 - 0,5.44 = 278(gam)$
$C\%_{HCl} = \dfrac{0,25.36,5}{278}.100\% = 3,28\%$
$C\%_{CaCl_2} = \dfrac{0,5.111}{278}.100\% = 19,96\%$