a, \(BaCl_2+H_2SO_4\rightarrow2HCl+BaSO_{4\downarrow}\)
b, \(m_{BaCl_2}=200.2,08\%=4,16\left(g\right)\Rightarrow n_{BaCl_2}=\dfrac{4,16}{208}=0,02\left(mol\right)\)
\(m_{H_2SO_4}=300.9,8\%=29,4\left(g\right)\Rightarrow n_{H_2SO_4}=\dfrac{29,4}{98}=0,3\left(mol\right)\)
Xét tỉ lệ: \(\dfrac{0,02}{1}< \dfrac{0,3}{1}\), ta được H2SO4 dư.
Theo PT: \(\left\{{}\begin{matrix}n_{BaSO_4}=n_{H_2SO_4\left(pư\right)}=n_{BaCl_2}=0,02\left(mol\right)\\n_{HCl}=2n_{BaCl_2}=0,04\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow n_{H_2SO_4\left(dư\right)}=0,3-0,02=0,28\left(mol\right)\)
Ta có: m dd sau pư = m dd BaCl2 + m dd H2SO4 - mBaSO4 = 200 + 300 - 0,02.233 = 495,34 (g)
\(\Rightarrow\left\{{}\begin{matrix}C\%_{HCl}=\dfrac{0,04.36,5}{495,34}.100\%\approx0,295\%\\C\%_{H_2SO_4\left(dư\right)}=\dfrac{0,28.98}{495,34}.100\%\approx5,54\%\end{matrix}\right.\)