a, \(n_{CuO}=\dfrac{4}{80}=0,05\left(mol\right)\)
PT: \(Cu\left(OH\right)_2\underrightarrow{t^o}CuO+H_2O\)
Theo PT: \(n_{Cu\left(OH\right)_2}=n_{CuO}=0,05\left(mol\right)\)
\(\Rightarrow m_{Cu\left(OH\right)_2}=0,05.98=4,9\left(g\right)\)
b, \(m_{H_2SO_4}=250.9,8\%=24,5\left(g\right)\Rightarrow n_{H_2SO_4}=\dfrac{24,5}{98}=0,25\left(mol\right)\)
PT: \(Cu\left(OH\right)_2+H_2SO_4\rightarrow CuSO_4+2H_2O\)
Xét tỉ lệ: \(\dfrac{0,05}{1}< \dfrac{0,25}{1}\), ta được H2SO4 dư.
Theo PT: \(n_{CuSO_4}=n_{H_2SO_4\left(pư\right)}=n_{Cu\left(OH\right)_2}=0,05\left(mol\right)\)
\(\Rightarrow n_{H_2SO_4\left(dư\right)}=0,25-0,05=0,2\left(mol\right)\)
\(\Rightarrow\left\{{}\begin{matrix}C\%_{CuSO_4}=\dfrac{0,05.160}{4,9+250}.100\%\approx3,14\%\\C\%_{H_2SO_4\left(dư\right)}=\dfrac{0,2.98}{4,9+250}.100\%\approx7,69\%\end{matrix}\right.\)