a)
\(n_{HCl\left(bđ\right)}=\dfrac{250.7,3\%}{36,5}=0,5\left(mol\right)\)
\(n_{khí}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\)
PTHH: Zn + 2HCl --> ZnCl2 + H2
ZnS + 2HCl --> ZnCl2 + H2S
Do nHCl(bđ) > 2.nkhí => HCl dư
Gọi số mol Zn, ZnS là a, b (mol)
=> 65a + 97b = 8,1 (1)
\(n_{khí}=n_{H_2}+n_{H_2S}=a+b=0,1\) (2)
(1)(2) => a = 0,05 (mol); b = 0,05 (mol)
\(\left\{{}\begin{matrix}m_{Zn}=0,05.65=3,25\left(g\right)\\m_{ZnS}=0,05.97=4,85\left(g\right)\end{matrix}\right.\)
nZnCl2 = 0,1 (mol) => mZnCl2 = 0,1.136 = 13,6 (g)
nHCl(dư) = 0,5 - 0,2 = 0,3 (mol) => mHCl = 0,3.36,5 = 10,95 (g)
mdd sau pư = 8,1 + 250 - 0,05.2 - 0,05.34 = 256,3 (g)
\(\left\{{}\begin{matrix}C\%_{ZnCl_2}=\dfrac{13,6}{256,3}.100\%=5,3\%\\C\%_{HCl\left(dư\right)}=\dfrac{10,95}{256,3}.100\%=4,3\%\end{matrix}\right.\)
b) \(\overline{M}_X=\dfrac{0,05.2+0,05.34}{0,05+0,05}=18\left(g/mol\right)\)
=> \(d_{X/H_2}=\dfrac{18}{2}=9\)