a.
\(n_S=\dfrac{16}{32}=0,5mol\)
Gọi \(\left\{{}\begin{matrix}n_{Zn}=x\\n_{Mg}=y\end{matrix}\right.\)
\(Zn+S\rightarrow\left(t^o\right)ZnS\)
x x ( mol )
\(Mg+S\rightarrow\left(t^o\right)MgS\)
y y ( mol )
Ta có:
\(\left\{{}\begin{matrix}65x+24y=23,4\\x+y=0,5\end{matrix}\right.\) \(\Leftrightarrow\left\{{}\begin{matrix}x=\dfrac{57}{205}\\y=\dfrac{91}{410}\end{matrix}\right.\)
\(\rightarrow\left\{{}\begin{matrix}m_{Zn}=\dfrac{57}{205}.65=\dfrac{741}{41}g\\m_{Mg}=\dfrac{91}{410}.24=\dfrac{1092}{205}g\end{matrix}\right.\)
\(\rightarrow\left\{{}\begin{matrix}\%m_{Zn}=\dfrac{741}{41}:23,4.100=77,23\%\\\%m_{Mg}=100\%-77,23\%=22,77\%\end{matrix}\right.\)
b.\(ZnS+2HCl\rightarrow ZnCl_2+H_2S\)
57/205 57/205 ( mol )
\(MgS+2HCl\rightarrow MgCl_2+H_2S\)
91/410 91/410 ( mol )
\(V_{H_2S}=\left(\dfrac{57}{205}+\dfrac{91}{410}\right).22,4=11,2l\)