a.
Gọi \(\left\{{}\begin{matrix}n_{CaCO_3}=x\left(mol\right)\\n_{MgCO_3}=y\left(mol\right)\end{matrix}\right.\)
Theo đề có hệ phương trình: \(\left\{{}\begin{matrix}100x+84y=4,68\\x+y=\dfrac{1,2395}{24,79}=0,05\end{matrix}\right.\Rightarrow\left\{{}\begin{matrix}x=0,03\\y=0,02\end{matrix}\right.\)
\(m_{CaCO_3}=0,03.100=3\left(g\right),m_{MgCO_3}=0,02.84=1,68\left(g\right)\)
b.
\(CM_{HCl}=\dfrac{2\left(x+y\right)}{0,25}=0,4\left(M\right)\)
\(n_{CO_2}=\dfrac{1,2395}{24,79}=0,05\left(mol\right)\)
PTHH:
\(CaCO_3+2HCl\rightarrow CaCl_2+H_2O+CO_2\)
x 2x x x x
\(MgCO_3+2HCl\rightarrow MgCl_2+H_2O+CO_2\)
y 2y y y y
Có hệ PT:
\(\left\{{}\begin{matrix}100x+84y=4,68\\x+y=0,05\end{matrix}\right.\)
\(\Leftrightarrow x=0,03;y=0,02\)
\(a,m_{CaCO_3}=0,03.100=3\left(g\right)\)
\(m_{MgCO_3}=4,68-3=1,68\left(g\right)\)
b, \(C_{M\left(HCl\right)}=\dfrac{0,1}{0,25}=\dfrac{2}{5}\left(M\right)\)
\(C_{M\left(CaCl_2\right)}=\dfrac{0,03}{0,25}=\dfrac{3}{25}\left(M\right)\)
\(C_{M\left(MgCl_2\right)}=\dfrac{0,02}{0,25}=\dfrac{2}{25}\left(M\right)\)