Question

Cần bao nhiêu ml dd X ( gồm HCl và CH3COOH )để trung hòa 25 ml dd hỗn hợp Ba(OH)2 0,02M và NaOH 0,05M. Biết Cm HCl = 0,1M, Cm CH3COOH = 0,2M

Answer 1

Ta có: \(n_{Ba\left(OH\right)_2}=0,025.0,02=0,0005\left(mol\right)\)

\(n_{NaOH}=0,025.0,05=0,00125\left(mol\right)\)

\(\Rightarrow n_{OH^-}=2n_{Ba\left(OH\right)_2}+n_{NaOH}=0,00225\left(mol\right)\)

\(H^++OH^-\rightarrow H_2O\)

\(\Rightarrow n_{H^+}=n_{OH^-}=0,00225\left(mol\right)\)

Gọi: V_X = x (l)

Ta có: \(n_{HCl}=0,1x\left(mol\right)\)

\(n_{CH_3COOH}=0,2x\left(mol\right)\)

\(\Rightarrow n_{H^+}=n_{HCl}+n_{CH_3COOH}=0,1x+0,2x=0,00225\)

\(\Rightarrow x=0,0075\left(l\right)=7,5\left(ml\right)\)