\(a,n_P=\dfrac{6,2}{31}=0,2\left(mol\right);n_{O_2}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\\ PTHH:4P+5O_2\rightarrow^{t^o}2P_2O_5\\ \text{Vì }\dfrac{n_P}{4}>\dfrac{n_{O_2}}{5}\Rightarrow P\text{ dư}\\ \Rightarrow n_{P\left(\text{p/ứ}\right)}=\dfrac{4}{5}n_{O_2}=0,16\left(mol\right)\\ \Rightarrow n_{P\left(dư\right)}=0,2-0,16=0,04\left(mol\right)\\ \Rightarrow\left\{{}\begin{matrix}m_{P\left(dư\right)}=0,04\cdot31=1,24\left(g\right)\\V_{P\left(dư\right)}=0,04\cdot22,4=0,896\left(l\right)\end{matrix}\right.\)
\(b,m_{P\left(\text{p/ứ}\right)}=0,16\cdot31=4,96\left(g\right)\\ m_{O_2}=0,2\cdot32=6,4\left(g\right)\\ C_1:BTKL:m_{P_2O_5}=m_P+m_{O_2}=4,96+6,4=11,36\left(g\right)\\ C_2:\text{Theo PTHH: }n_{P_2O_5}=\dfrac{2}{5}n_{O_2}=0,08\left(mol\right)\\ \Rightarrow m_{P_2O_5}=0,08\cdot142=11,36\left(g\right)\)