Đề bài phải là thể tích CO2 bạn nhé!
a, PT: \(CaCO_3+2HCl\rightarrow CaCl_2+H_2O+CO_2\)
Ta có: \(n_{CaCO_3}=\dfrac{4}{100}=0,04\left(mol\right)\)
\(m_{HCl}=\dfrac{14,6.25}{100}=3,65\left(g\right)\Rightarrow n_{HCl}=\dfrac{3,65}{36,5}=0,1\left(mol\right)\)
Xét tỉ lệ: \(\dfrac{0,04}{1}< \dfrac{0,1}{2}\), ta được HCl dư.
Theo PT: \(n_{CO_2}=n_{CaCO_3}=0,04\left(mol\right)\)
\(\Rightarrow V_{CO_2}=0,04.22,4=0,896\left(l\right)\)
b, Theo PT: \(\left\{{}\begin{matrix}n_{HCl\left(pư\right)}=2n_{CaCO_3}=0,08\left(mol\right)\\n_{CaCl_2}=n_{CaCO_3}=0,04\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow n_{HCl\left(dư\right)}=0,02\left(mol\right)\Rightarrow m_{HCl\left(dư\right)}=0,02.36,5=0,73\left(g\right)\)
\(m_{CaCl_2}=0,04.111=4,44\left(g\right)\)
Bạn tham khảo nhé!
PTHH: \(CaCO_3+2HCl\rightarrow CaCl_2+H_2O+CO_2\uparrow\)
Ta có: \(\left\{{}\begin{matrix}n_{CaCO_3}=\dfrac{4}{100}=0,04\left(mol\right)\\n_{HCl}=\dfrac{14,6\cdot25\%}{36,5}=0,1\left(mol\right)\end{matrix}\right.\)
Xét tỉ lệ: \(\dfrac{0,04}{1}< \dfrac{0,1}{2}\) \(\Rightarrow\) HCl còn dư, CaCO3 p/ứ hết
\(\Rightarrow\left\{{}\begin{matrix}n_{CO_2}=n_{CaCl_2}=0,04\left(mol\right)\\n_{HCl\left(dư\right)}=0,02\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}V_{CO_2}=0,04\cdot22,4=0,896\left(l\right)\\m_{CaCl_2}=0,04\cdot111=4,44\left(g\right)\\m_{HCl\left(dư\right)}=0,02\cdot36,5=0,73\left(g\right)\end{matrix}\right.\)