ZnCl2 + 2KOH -> Zn(OH)2 + 2KCl (1)
nZnCl2=0,2(mol)
Theo PTHH 1 ta có:
nZnCl2=nZn(OH)2=0,2(mol)
mZn(OH)2=99.0,2=19,8(g)
b;
ZnCl2 + 2KOH -> Zn(OH)2 + 2KCl (2)
2KOH + Zn(OH)2 -> K2ZnO2 + 2H2O (3)
nKOH=0,8(mol)
Vì 0,2.2<0,8 nên KOH dư 0,4 mol
Vì \(\dfrac{0,4}{2}=0,2\) nên ở 3 xảy ra vừa đủ
Trong dd chỉ có KCl và K2ZnO2
Bạn tự tỉnh tiếp nha
a)
\(n_{ZnCl_2}=\dfrac{m}{M}=\dfrac{27,2}{136}=0,2mol\)
ZnCl2+2KOH\(\rightarrow\)Zn(OH)2\(\downarrow\)+2KCl
0,2\(\rightarrow\).....................0,2
\(m_{Zn\left(OH\right)_2}=0,2.99=19,8gam\)
b)\(n_{ZnCl_2}=0,2mol\)
\(n_{KOH}=\dfrac{44,8}{56}=0,8mol\)
ZnCl2+2KOH\(\rightarrow\)Zn(OH)2\(\downarrow\)+2KCl
-Tỉ lệ: \(\dfrac{0,2}{1}< \dfrac{0,8}{2}\rightarrow\)KOH dư
ZnCl2+2KOH\(\rightarrow\)Zn(OH)2\(\downarrow\)+2KCl
0,2\(\rightarrow\).....0,4...........0,2..............0,4
\(n_{KCl}=0,4mol\rightarrow m_{KCl}=0,4.74,5=29,8gam\)
\(n_{KOH\left(dư\right)}=0,8-0,4=0,4mol\rightarrow m_{KOH}=0,4.56=22,4gam\)
\(m_{dd}=27,2+200-19,8=207,4gam\)
C%KCl=\(\dfrac{29,8.100}{207,4}\approx14,37\%\)
C%KOH=\(\dfrac{22,4.100}{207,4}\approx10,8\%\)