\(n_{Al}=\dfrac{8,1}{27}=0,3(mol);n_{HCl}=\dfrac{21,9}{36,5}=0,6(mol)\\ a,PTHH:2Al+6HCl\to 2AlCl_3+3H_2\\ LTL:\dfrac{0,3}{2}>\dfrac{0,6}{6}\Rightarrow Al\text { dư}\\ n_{Al(dư)}=0,3-\dfrac{0,6}{3}=0,1(mol)\\ \Rightarrow m_{Al(dư)}=0,1.27=2,7(g)\\ c,n_{AlCl_3}=\dfrac{1}{3}n_{HCl}=0,2(mol)\\n_{H_2}=\dfrac{1}{2}n_{HCl}=0,3(mol)\\ \Rightarrow m_{AlCl_3}=0,2.133,5=26,7(g)\\ d,V_{H_2}=0,3.22,4=6,72(l)\)