Gọi số mol Al là x, FeO là y
\(\Rightarrow27x+72y=12,6\)
Phản ứng xảy ra:
\(2Al+6HCl\rightarrow2AlCl_3+3H_2\)
\(FeO+2HCl\rightarrow FeCl_2+H_2O\)
Ta có:
\(n_{AlCl3}=n_{Al}=x;n_{FeCl2}=n_{FeO}=y\)
\(\Rightarrow y=133,5x+127y=39,4\)
\(\Rightarrow\left\{{}\begin{matrix}x=0,2\\y=0,1\end{matrix}\right.\)
\(V_{dd}=200\left(ml\right)=0,2\left(l\right)\)
\(\Rightarrow CM_{AlCl3}=\frac{0,2}{0,2}=1M\)
\(\Rightarrow CM_{FeCl2}=\frac{0,1}{0,2}=0,5M\)
\(\left\{{}\begin{matrix}27n_{Al}+72n_{FeO}=12,6\\133,5n_{Al}+127n_{FeO}=39,4\end{matrix}\right.\)
nAl=0,2;nFeO=0,1
%mAl=\(\frac{0,2.27}{12,6}.100\%=42,86\%\)
%mFeO=100-42,86=57,14%
CM dd FeCl2=\(\frac{0,1}{0,2}=0,5M\)
CM dd AlCl3=\(\frac{0,2}{0,2}=1M\)
a)
2Al + 6HCl ----> 2AlCl3 + 3H2
x_________________x
FeO + 2HCl ----> FeCl2 + H2
y__________________y
\(\Rightarrow\left\{{}\begin{matrix}27x+72y=12,6\\133,5x+127y=39,4\end{matrix}\right.\Rightarrow\left\{{}\begin{matrix}x=0,2\\y=0,1\end{matrix}\right.\\ \Rightarrow\%FeO=57,14\%;\\ \%Al=42,86\%\)
\(C_{M\left(AlCl_3\right)}=1\left(M\right);C_{M\left(FeCl_2\right)}=0,5\left(M\right)\)