a/ Ta có: \(n_{KClO_3}=\dfrac{12.25}{122.5}=0.1\left(mol\right)\)
PTHH:
\(2KClO_3\underrightarrow{t^o}2KCl+3O_2\uparrow\)
2 3
0.1 x
\(=>x=\dfrac{0.1\cdot3}{2}=0.15=n_{O_2}\)
\(=>V_{O_2}=0.15\cdot22.4=3.36\left(l\right)\)
PTHH: \(KClO_3\underrightarrow{t^o}KCl+\dfrac{3}{2}O_2\)
a) Ta có: \(n_{KClO_3}=\dfrac{12,25}{122,5}=0,1\left(mol\right)\)
\(\Rightarrow n_{O_2}=0,15\left(mol\right)\) \(\Rightarrow V_{O_2}=0,15\cdot22,4=3,36\left(l\right)\)
b) PTHH: \(3Fe+2O_2\underrightarrow{t^o}Fe_3O_4\)
Ta có: \(n_{Fe}=\dfrac{11,2}{56}=0,2\left(mol\right)\)
Xét tỉ lệ: \(\dfrac{0,2}{3}< \dfrac{0,15}{2}\) \(\Rightarrow\) Oxi còn dư, Fe p/ứ hết
\(\Rightarrow n_{Fe_3O_4}=\dfrac{1}{15}\left(mol\right)\) \(\Rightarrow m_{Fe_3O_4}=\dfrac{1}{15}\cdot232\approx15,47\left(g\right)\)
\(n_{KClO_3}=\dfrac{m_{KClO_3}}{M_{KClO_3}}=\dfrac{12,25}{122,5}=0,1\left(mol\right)\\ PTHH:2KClO_3\underrightarrow{t^o}2KCl+3O_2\\ n_{O_2}=\dfrac{3}{2}n_{KClO_3}=\dfrac{3}{2}\cdot0,1=0,15\left(mol\right)\\ V_{O_2\left(ĐKTC\right)}=n_{O_2}\cdot22,4=0,15\cdot22,4=3,36\left(l\right)\\ n_{Fe}=\dfrac{m_{Fe}}{M_{Fe}}=\dfrac{11,2}{56}=0,2\left(mol\right)\\ PTHH:3Fe+2O_2\underrightarrow{t^o}Fe_3O_4\\ \dfrac{n_{Fe}}{n_{O_2}}=2>\dfrac{3}{2}\Rightarrow Fe\text{ dư, bài toán tính theo lượng }O_2\\ m_{Fe_3O_4}=n_{Fe_3O_4}\cdot M_{Fe_3O_4}=0,075\cdot232=17,4\left(g\right)\)