Bài 1 :
\(CT:C_nH_{2n-6}\left(n\ge6\right)\)
\(\%C=\dfrac{12n}{14n-6}\cdot100\%=90.57\%\)
\(\Rightarrow n=8\)
\(CT:C_8H_{10}\)
Bài 2 :
\(n_{CO_2}=\dfrac{17.6}{44}=0.4\left(mol\right)\)
\(CT:C_nH_{2n+1}OH\)
\(\Rightarrow n_{ancol}=\dfrac{n_{CO_2}}{n}=\dfrac{0.4}{n}\left(mol\right)\)
\(M_A=\dfrac{7.4}{\dfrac{0.4}{n}}=\dfrac{37}{2}n\left(\dfrac{g}{mol}\right)\)
\(\Rightarrow14n+18=\dfrac{37}{2}n\)
\(\Rightarrow n=4\)
\(CT:C_4H_9OH\)
\(CTCT:\)
\(B1:\)
\(CH_3-CH_2-CH_2-CH_2-OH:butan-1-ol\)
\(B2:\)
\(CH_3-CH_2-CH\left(CH_3\right)-OH:butan-2-ol\)
\(B2:\)
\(CH_3-CH\left(CH_3\right)-CH_2-OH:2-metylpropan-1-ol\)
\(B3:\)
\(C\left(CH_3\right)_3-OH:2-metylpropan-2-ol\)
Bài 1 :
CTPT X: CnH2n-6
Ta có :
\(\%C = \dfrac{12n}{14n-6}.100\% = 90,57\%\\ \Rightarrow n = 8\)
Vậy CTPT của X: C8H10
Bài 2 :
Ancol : CnH2n+2O
Ta có :
\(n_C = n_{CO_2} = \dfrac{17,6}{44}= 0,4(mol)\\ \Rightarrow m_C = 0,4.12 = 4,8(gam)\)
Ta có :
\(\dfrac{m_C}{m_{ancol}} = \dfrac{12n}{14n + 18} = \dfrac{4,8}{7,4}\\ \Rightarrow n = 4\)
Vậy, CTCT :
\(CH_3-CH_2-CH_2-CH_2-OH\) : butan-1-ol (Ancol bậc 1)
\(CH_3-CH(CH_3)-CH_2-OH\) : 2-metyl propan-1-ol (Ancol bậc 1)
\(CH_3-C(OH)(CH_3)-CH_3\) : 2-metyl propan-2-ol (Ancol bậc 3)
\(CH_3-CH(OH)-CH_2-CH_3\) : butan-2-ol (Ancol bậc 2)
Bài 4 :
\(CT:C_{\overline{n}}H_{2\overline{n}+1}OH\)
\(n_{H_2}=\dfrac{2.24}{22.4}=0.1\left(mol\right)\)
\(C_{\overline{n}}H_{2\overline{n}+1}OH+Na\rightarrow C_{\overline{n}}H_{2\overline{n}+1}ONa+\dfrac{1}{2}H_2\)
\(\Rightarrow n_A=2n_{H_2}=2\cdot0.1=0.2\left(mol\right)\)
\(M_A=\dfrac{10.6}{0.2}=53\left(\dfrac{g}{mol}\right)\)
\(\Leftrightarrow14\overline{n}+18=53\)
\(\Leftrightarrow\overline{n}=2.5\)
\(CT:C_2H_5OH,C_3H_7OH\)