a) 2KClO3 \(\underrightarrow{to}\) 2KCl + 3O2 (1)
2KNO3 \(\underrightarrow{to}\) 2KNO2 + O2 (2)
b) Theo PT1: \(n_{O_2}=\dfrac{3}{2}n_{KClO_3}=\dfrac{3}{2}\times0,1=0,15\left(mol\right)\)
\(\Rightarrow V_{O_2}\left(1\right)=0,15\times22,4=3,36\left(l\right)\)
Theo PT2: \(n_{O_2}=\dfrac{1}{2}n_{KNO_3}=\dfrac{1}{2}\times0,1=0,05\left(mol\right)\)
\(\Rightarrow V_{O_2}\left(2\right)=0,05\times22,4=1,12\left(l\right)\)
Vậy nếu dùng 0,1 mol mỗi chất trên thì thể tích khí oxi thu được khác nhau
c) \(n_{O_2}=\dfrac{1,12}{22,4}=0,05\left(mol\right)\)
Theo PT1: \(n_{KClO_3}=\dfrac{2}{3}n_{O_2}=\dfrac{2}{3}\times0,05=\dfrac{1}{30}\left(mol\right)\)
\(\Rightarrow m_{KClO_3}=\dfrac{1}{30}\times122,5=4,083\left(g\right)\)
Theo PT2: \(n_{KNO_3}=2n_{O_2}=2\times0,05=0,1\left(mol\right)\)
\(\Rightarrow m_{KNO_3}=0,1\times101=10,1\left(g\right)\)