Tron CuA voi oxit cua kim loại M chi co hoa tri (II) theo ti le so moi tuong ung la 1:2 dc hh A. Cho 4,8g A vao ong su, nung nong, roi dan luong khi CO du di qua, ket thúc pu thu dc hh ran B. B phan ung vua du voi 160ml dd HNO3 1,25M, thu dc dd chua 2 muoi va chi co khi NO thoát ra voi the tich la V lia ( o đktc) .Tim kim loại M ,tinh V
CuO + CO -to-> Cu +CO2 (1)
MO + CO -to-> M +CO2 (2)
3Cu + 8HNO3 --> 3Cu(NO3)2 +2NO +4H2O (3)
3M +8HNO3 --> 3M(NO3)2 +2NO + 4H2O (4)
nHNO3=0,2(MOL)
theo (3,4) : nNO=1/4nHNO3=0,05(mol)
=>VNO(đktc)=1,12(l)
theo (1,2,3,4) :nCuO,MO=3/8nHNO3=0,075 (mol)
mà nCuO:nMO=1:2
=> nCuO=0,025(mol)
nMO=0,05(mol)
=>mCuO=2(g)(g)=>mMO=2,8(g)
=>MM=\(\dfrac{2,8}{0,05}=56\)(g/mol)
=> M:Fe
CuO+CO\(\rightarrow\)Cu+CO2
a.....................a(mol)
MO+CO\(\rightarrow\)M+CO2
2a...............2a(mol)
3Cu+8HNO3\(\rightarrow\)3Cu(NO3)2+2NO+4H2O
a............8a/3............................2a/3(mol)
3M+8HNO3\(\rightarrow\)3M(NO3)2+2NO+4H2O
2a.........16a/3...........................4a/3(mol)
nHNO3=1,25.0,16=0,2(mol)
Theo pthh: \(\dfrac{8a}{3}+\dfrac{16a}{3}=0,2\Leftrightarrow a=0,025\left(mol\right)\)
\(\Rightarrow\)VNO=\(\dfrac{2.0,025}{3}+\dfrac{4.0,025}{3}=0,05.22,4=1,12\left(l\right)\)
Ta có: 64.a+M.2a=4,8\(\)mà a=0,025
\(\Rightarrow\)M=40(Ca)
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