1.
2Fe + 6H2SO4(đ) \(\underrightarrow{t^o}\)Fe2(SO4)3 + 3SO2 + 6H2O (1)
Fe + 3H2SO4(đ) \(\underrightarrow{t^o}\)Fe2(SO4)3 + 3H2O (2)
Theo PTHH 1 ta có:
\(\dfrac{3}{2}\)nFe=nSO2=0,3(mol)
VSO2=22,4.0,3=6,72(lít)
2.
2Fe + 6H2SO4(đ) \(\underrightarrow{t^o}\)Fe2(SO4)3 + 3SO2 + 6H2O (1)
Fe2O3 + 3H2SO4(đ) \(\underrightarrow{t^o}\)Fe2(SO4)3 + 3H2O (2)
Theo PTHH 1 và 2 ta có:
\(\dfrac{1}{2}\)nFe=nFe2(SO4)3=0,1(mol)
nFe2O3=nFe2(SO4)3=0,1(mol)
mmuối=0,2.400=80(g)
2.nFe(Fe2O3)=0.1.2=0.2mol
nFe trc pứ=0.2+0.2=0.4mol
nFe[Fe2(SO4)3]=nFe trc pứ=0.4mol
=>nFe(SO4)3=0.4/2=0.2mol
mFe2(SO4)3=400.0.2=80g.
Vậy m=80g.
nFe(Fe2O3)=0.1.2=0.2mol
nFe trc pứ=0.2+0.2=0.4mol
nFe[Fe2(SO4)3]=nFe trc pứ=0.4mol
=>nFe(SO4)3=0.4/2=0.2mol
mFe2(SO4)3=400.0.2=80g.
Vậy m=80g.