PTHH: \(CaCO_3+2HCl\rightarrow CaCl_2+H_2O+CO_2\uparrow\)
a) Ta có: \(n_{CaCO_3}=\dfrac{2,5}{100}=0,025\left(mol\right)\)
\(\Rightarrow n_{HCl}=0,05mol\) \(\Rightarrow m_{ddHCl}=\dfrac{0,05\cdot36,5}{18\%}\approx10,14\left(g\right)\)
b) Theo PTHH: \(n_{CaCl_2}=n_{CO_2}=n_{CaCO_3}=0,025\left(mol\right)\)
\(\Rightarrow\left\{{}\begin{matrix}m_{CaCl_2}=0,025\cdot111=2,775\left(g\right)\\m_{CO_2}=0,025\cdot44=1,1\left(g\right)\end{matrix}\right.\)
Mặt khác: \(m_{dd\left(saup/ứ\right)}=m_{Zn}+m_{ddHCl}-m_{CO_2}=11,54\left(g\right)\)
\(\Rightarrow C\%_{CaCl_2}=\dfrac{2,775}{11,54}\cdot100\%\approx24,05\%\)
CaCO3+2HCl→CaCl2+CO2↑ +H2O
\(+n_{CaCO_3}=\dfrac{2,5}{100}=0,025\left(mol\right)\)
\(+n_{HCl}=2n_{CaCO_3}=0,05\left(mol\right)\)
\(+m_{HCl}=0,05.98=4,9\left(gam\right)\)
\(+m_{dungdịchHCl}=\dfrac{4,9}{18}.100\%=27,2\left(gam\right)\)
\(+n_{CaCl}=n_{CaCO_3}=0,025\left(mol\right)\)
\(+m_{CaCl_2}=0,025.111=2,775\left(gam\right)\)
Theo ĐLBTKL ta có:
\(m_{CaCl_2}=2,5+27,2-0,025.44-0,025.18=28,15\left(gam\right)\)
C%=\(\dfrac{2,775}{28,15}.100\%\approx9,85\%\)
