a)
$Fe + 2HCl \to FeCl_2 + H_2$
$Zn + 2HCl \to ZnCl_2 + H_2$
$2Al + 6HCl \to 2AlCl_3 + 3H_2$
$n_{HCl} = 0,45.2 = 0,9(mol)$
Theo PTHH :
$n_{H_2} = \dfrac{1}{2}n_{HCl} = 0,45(mol)$
$V_{H_2} = 0,45.22,4 = 10,08(lít)$
b)
Bảo toàn khối lượng :
$m_{muối} = 21,3 + 0,9.36,5 - 0,45.2 = 53,25(gam)$