2Na + 2H2O --> 2NaOH + H2; (1)
0,2-------------------0,2--------0,1 (mol)
Na2O + H2O --> 2NaOH; (2)
0,31--------------------0,62 (mol)
ta có: nH2= 2,24/22,4=0,1 (mol)
=> nNaOH (1)= 0,2 (mol)
=> nNa= 0,2(mol)=> mNa= 0,2*23= 4,6(g)
=> mNaOH= 17-4,6= 12,4 (g)=> nNaOH= 12,4/40= 0,31 (mol)
=> nNaOH (2)= 0,31*2= 0,62(mol)
=> nNaOH sr= 0,2+0,62= 0,82 (mol)
V dd= 0,5(l)
Cm dd A= 0,82/0,5= 1,64 (M)
nH2=V/22,4=0,1(mol)
PT1: 2Na + 2H2O -> 2NaOH + H2
PT2: Na2O + H2O -> 2NaOH
Theo 2PT thì chỉ có pt1 có khí H2 bay lên
=> nNa(PT1)=nNaOH(PT1)=2.nH2=2.0,1=0,2(mol)
=>mNa=n.M=0,2.23=4,6(g)
=> mNa2O=mh h -mNa=17-4,6=12,4(g)
từ đó ,ta có: nNa2o=m/M=12,4/62=0,2(mol)
=> nNaOH(pt2)=2.nNa2O=2.0,2=0,4(mol)
=> nNaOH(cả 2pt)=0,2+0,4=0,6(mol)
Vd dA=Vnước=500ml=0,5(lít)
=> CM d d A=n/V=0,6/0,5=1,2(M)