a)
$MCl_2 + H_2SO_4 \to MSO_4 + 2HCl$
$n_{MCl_2}= n_{MSO_4}$
$\Rightarrow \dfrac{31,2}{M + 71} = \dfrac{34,95}{M + 96}$
$\Rightarrow M = 137(Bari)$
b)
$n_{H_2SO_4} = n_{BaSO_4} = \dfrac{34,95}{233} = 0,15(mol)$
$m_{dd\ H_2SO_4} = \dfrac{0,15.98}{20\%} = 73,5(gam)$
c)
$n_{HCl} = 2n_{BaSO_4} = 0,3(mol)$
$m_{dd}= 31,2 + 73,5 - 34,95 = 69,75(gam)$
$C\%_{HCl} = \dfrac{0,3.36,5}{69,75}.100\% = 15,7\%$